@article{oai:repo.qst.go.jp:00045440, author = {Takata, Hyoe and Tagami, Keiko and Aono, Tatsuo and Uchida, Shigeo and 高田 兵衛 and 田上 恵子 and 青野 辰雄 and 内田 滋夫}, issue = {1}, journal = {Atomic Scpectroscopy}, month = {Mar}, note = {The use of a solid-phase extraction column packed with a polyamino-polycarboxylic acid chlating resin (NOBIASCHELATE resin) for separation and concentration of trace levels of yttrium (Y) and rare earth elements (REEs) from estuarine and coastal water samples is described. The Y and REE recoveries from the resin were pH dependent; at pH 5.7, Y and REEs were extracted from the resin with almost 100% recovery. Barium, which has the potential to interfere with the analysis of REEs by inductively coupled plasma mass spectrometry (ICP-MS) because of the formation of oxide complexes, was not recovered from the column at pH 5.7. In addition, the reproducibility of the results for Y and REEs was not affected by variations in salinity or by high concentrations of heavy metals, such as Fe, Mn, and Mo. The method was verified by the analysis of a coastal water standard reference material (NRCC CASS-4). The values obtained with the present method were comparable to previously reported values obtained by standard analytical techniques. We used this simple, quick method to determine the concentrations of Y and REEs in estuarine and coastal waters of the Mabechi River and off Aomori, Japan.}, pages = {10--19}, title = {Determination of Trace Levels of Yttrium and Rare Earth Elements in Estuarine and Coastal Waters by Inductively Coupled Plasma Mass Spectrometry Following Preconcentration with NOBIAS-CHELATE Resin}, volume = {30}, year = {2009} }