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  1. 原著論文

Is soft X-ray irradiation of a high-LET like nature? -dependence of X-ray energy in cross-linking yield of polydimethylsiloxane and halogenated polystyrenes

https://repo.qst.go.jp/records/2002616
https://repo.qst.go.jp/records/2002616
f6780c34-2e2f-40c4-9712-a5ed9981d8cf
アイテムタイプ 学術雑誌論文 / Journal Article(1)
公開日 2026-01-20
タイトル
タイトル Is soft X-ray irradiation of a high-LET like nature? -dependence of X-ray energy in cross-linking yield of polydimethylsiloxane and halogenated polystyrenes
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Seiko Nakagawa

× Seiko Nakagawa

Seiko Nakagawa

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Ohara Maki

× Ohara Maki

Ohara Maki

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Yokoya Akinari

× Yokoya Akinari

Yokoya Akinari

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Noriko Usami

× Noriko Usami

Noriko Usami

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抄録
内容記述タイプ Abstract
内容記述 In a previous study, we investigated the dose response of alanine dosimeters irradiated with 2.0–7.0 keV monochromatic X-rays and found that the soft X-ray irradiation should be a high-LET like nature (Radiat. Phys. Chem. 214, 111304). The lower energy of Auger- and photo-electrons ejected from the irradiated materials will cause high LET irradiation. This suggests that soft X-ray irradiation can induce the effective cross-linking of polymer. In the present study, we examined the cross-linking behavior of polydimethylsiloxane and halogenated polystyrenes under 2.5–5.0 keV monochromatic X-ray irradiations. The cross-linking yield increased with the dose and saturated at significantly lower dose than those achieved with high-energy photons or electrons. The result is the reverse trend of alanine radical yield observed in the previous study. The cross-linking yields of halogenated polystyrenes highlight the influence of Auger- and photoelectron energies modulated by both halogen substitution and the energy of X-rays on the cross-linking process. Finally, cross-linking efficiency can be controlled by the type of element present in the polymer and X-ray energy.
書誌情報 Radiation Physics and Chemistry

巻 242, p. 113635, 発行日 2026-01
出版者
出版者 Elsevier
DOI
識別子タイプ DOI
関連識別子 10.1016/j.radphyschem.2026.113635
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