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  1. 原著論文

Valence/spin states of iron in peridotite glass to megabar pressure implications for dense ferric-iron-rich silicate melt at the bottom of the mantle

https://repo.qst.go.jp/records/2001327
https://repo.qst.go.jp/records/2001327
80204d1c-18b6-4a72-b82d-e9f3b327ff0b
アイテムタイプ 学術雑誌論文 / Journal Article(1)
公開日 2025-04-18
タイトル
タイトル Valence/spin states of iron in peridotite glass to megabar pressure implications for dense ferric-iron-rich silicate melt at the bottom of the mantle
言語 en
言語
言語 eng
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ journal article
著者 Izumi Mashino

× Izumi Mashino

Izumi Mashino

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Takashi Yoshino

× Takashi Yoshino

Takashi Yoshino

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Takaya Mitsui

× Takaya Mitsui

Takaya Mitsui

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Kosuke Fujiwara

× Kosuke Fujiwara

Kosuke Fujiwara

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Sayako Inoue

× Sayako Inoue

Sayako Inoue

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Takeshi Sakai

× Takeshi Sakai

Takeshi Sakai

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抄録
内容記述タイプ Abstract
内容記述 We have conducted electrical conductivity and energy-domain synchrotron Mossbauer spectroscopic measurements of peridotite glass as an analogue of silicate melts at the bottom of the mantle. The changes in the Mossbauer parameters and the change in the trend of the electrical conductivity profile have been observed at around 80 GPa, suggesting that the structural change of the glass from akimotoite-like to postperovskite-like structures. We also observed the changes in the Mossbauer parameters above 120 GPa, which might be due to the change in near-neighbor coordination number to iron. On the other hand, we did not observe the trend change in the electrical conductivity. This means that the effect of the coordination number change on the electrical conductivity is small. The pressure conditions of these changes in structure and coordination number are much lower than the lowermost mantle pressure, that is, the melt would become compact at the bottom of the mantle.
書誌情報 Geophysical Research Letters

巻 52, 号 7, p. e2024GL113106, 発行日 2025-04
ISSN
収録物識別子タイプ ISSN
収録物識別子 0094-8276
DOI
識別子タイプ DOI
関連識別子 10.1029/2024GL113106
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