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内容記述 |
Mossbauer diffraction is a technique to measure a site-selective spectrum, which may enable us to obtain precise hyperfine parameters. The information about the electronic state, spin state, and local structure of Fe will lead to fabricate novel materials and new functional materials. Here we review our development of a synchrotron 57Fe Mossbauer diffractometer at BL11XU SPring-8 and its application to functional materials. In order to collect only the nuclear resonant scattering, which is relevant to a site-selective spectrum, we have proposed three methods; the 45o method, pure nuclear method, and polarization analyzer method. Thus, we have succeeded in obtaining the crystal-site-selective spectra of some multi-Fe-sites oxides, such as Fe3O4, Fe3BO6, and Y3Fe5O12. At present, the apparatus is equipped by a four-circle diffractometer instead of the former θ-2θ goniometer, and has high sensitivity to measure the signals even from the natural iron samples. In this paper, we also report our recent results on the crystal-site-selective spectra of the high temperature phase of Fe3O4, the examination of the charge ordered state of the low temperature phase of Fe3O4, and the crystal-site-selective spectra of the high temperature phase of Y3Fe5O12. |
