WEKO3
アイテム
{"_buckets": {"deposit": "c9249b4c-528b-43a5-a99c-c508c32c0743"}, "_deposit": {"created_by": 1, "id": "86196", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "86196"}, "status": "published"}, "_oai": {"id": "oai:repo.qst.go.jp:00086196", "sets": ["1"]}, "author_link": ["1052254", "1052250", "1052255", "1052256", "1052252", "1052260", "1052259", "1052251", "1052257", "1052253", "1052258", "1052249"], "item_8_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2022-05", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "4028", "bibliographicPageStart": "4024", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "Organic Letters"}]}]}, "item_8_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Scandium triflate-catalyzed N-[18F]fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin ([18F]2) was investigated. This reaction is mild and provides one-step access to N-[18F]fluoroalkylated aryl- or heteroaryl-amines, which are used for positron emission tomography imaging. Use of 2,2,2-trifluoroethanol as a cosolvent improved the re-action efficiency. The use of (S)- or (R)-[18F]2 produced the corresponding enantiomeric N-[18F]fluoroalkylated anilines. ", "subitem_description_type": "Abstract"}]}, "item_8_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Chemical Society"}]}, "item_8_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1021/acs.orglett.2c01459", "subitem_relation_type_select": "DOI"}}]}, "item_8_relation_17": {"attribute_name": "関連サイト", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1021/acs.orglett.2c01459", "subitem_relation_type_select": "DOI"}}]}, "item_8_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1523-7052", "subitem_source_identifier_type": "ISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "metadata only access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_14cb"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Masayuki, Fujinaga"}], "nameIdentifiers": [{"nameIdentifier": "1052249", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohkubo, Takayuki"}], "nameIdentifiers": [{"nameIdentifier": "1052250", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tomoteru, Yamasaki"}], "nameIdentifiers": [{"nameIdentifier": "1052251", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Katsushi, Kumata"}], "nameIdentifiers": [{"nameIdentifier": "1052252", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nobuki, Nengaki"}], "nameIdentifiers": [{"nameIdentifier": "1052253", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Zhang, Ming-Rong"}], "nameIdentifiers": [{"nameIdentifier": "1052254", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Masayuki, Fujinaga", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "1052255", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohkubo, Takayuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "1052256", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tomoteru, Yamasaki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "1052257", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Katsushi, Kumata", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "1052258", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nobuki, Nengaki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "1052259", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Zhang, Ming-Rong", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "1052260", "nameIdentifierScheme": "WEKO"}]}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Scandium triflate-catalyzed N-[18F]Fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin under mild condi-tions", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Scandium triflate-catalyzed N-[18F]Fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin under mild condi-tions"}]}, "item_type_id": "8", "owner": "1", "path": ["1"], "permalink_uri": "https://repo.qst.go.jp/records/86196", "pubdate": {"attribute_name": "公開日", "attribute_value": "2022-05-23"}, "publish_date": "2022-05-23", "publish_status": "0", "recid": "86196", "relation": {}, "relation_version_is_last": true, "title": ["Scandium triflate-catalyzed N-[18F]Fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin under mild condi-tions"], "weko_shared_id": -1}
Scandium triflate-catalyzed N-[18F]Fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin under mild condi-tions
https://repo.qst.go.jp/records/86196
https://repo.qst.go.jp/records/861966d66bc4e-6632-4bde-9763-019fc7551aef
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2022-05-23 | |||||
タイトル | ||||||
タイトル | Scandium triflate-catalyzed N-[18F]Fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin under mild condi-tions | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Masayuki, Fujinaga
× Masayuki, Fujinaga× Ohkubo, Takayuki× Tomoteru, Yamasaki× Katsushi, Kumata× Nobuki, Nengaki× Zhang, Ming-Rong× Masayuki, Fujinaga× Ohkubo, Takayuki× Tomoteru, Yamasaki× Katsushi, Kumata× Nobuki, Nengaki× Zhang, Ming-Rong |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Scandium triflate-catalyzed N-[18F]fluoroalkylation of aryl- or heteroaryl-amines with [18F]epifluorohydrin ([18F]2) was investigated. This reaction is mild and provides one-step access to N-[18F]fluoroalkylated aryl- or heteroaryl-amines, which are used for positron emission tomography imaging. Use of 2,2,2-trifluoroethanol as a cosolvent improved the re-action efficiency. The use of (S)- or (R)-[18F]2 produced the corresponding enantiomeric N-[18F]fluoroalkylated anilines. | |||||
書誌情報 |
Organic Letters 巻 24, p. 4024-4028, 発行日 2022-05 |
|||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1523-7052 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/acs.orglett.2c01459 | |||||
関連サイト | ||||||
識別子タイプ | DOI | |||||
関連識別子 | https://doi.org/10.1021/acs.orglett.2c01459 |