WEKO3
アイテム
{"_buckets": {"deposit": "76c36f7e-caee-494e-a4d3-74152ea7b582"}, "_deposit": {"created_by": 1, "id": "49137", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "49137"}, "status": "published"}, "_oai": {"id": "oai:repo.qst.go.jp:00049137", "sets": ["1"]}, "author_link": ["495742", "495739", "495738", "495736", "495735", "495741", "495737", "495743", "495740"], "item_8_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2018-08", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "193-11", "bibliographicPageStart": "193-1", "bibliographicVolumeNumber": "25", "bibliographic_titles": [{"bibliographic_title": "Journal of Polymer Research"}]}]}, "item_8_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Grafted polymer substrates bearing diglycol amic acid (DA) ligands for Eu and Sm adsorption were prepared using a two-step post-grafting modification of polyethylene/polypropylene-g-poly(glycidyl methacrylate) (PE/PP-g-PGMA) that was synthesized through reversible addition-fragmentation chain transfer (RAFT)-mediated γ-radiation induced graft polymerization in emulsion phase. The PE/PP-g-PGMA prepared with RAFT mediation exhibited better reactivity towards amination reaction at 40 °C than the graft copolymers prepared without RAFT mediation, with the epoxide to amino group conversion of the former exceeding the latter by as much as 20%. The DA ligands were incorporated to the aminated graft copolymer by subsequent reaction with diglycolic anhydride to yield theDA-modified PE/PP-g-PGMAadsorbent. The effects of pH and competing ions on the uptake of Eu and Sm have been investigated. The DA-modified PE/PP-g-PGMA prepared with RAFT mediation showed higher Eu and\nSm adsorption percentage than the DA adsorbent that was synthesized without RAFT mediation. The DA-modified PE/PP-g-PGMA exhibited higher affinity for Eu over Cu and Fe in acidic solutions.", "subitem_description_type": "Abstract"}]}, "item_8_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Springer"}]}, "item_8_relation_14": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1007/s10965-018-1585-4 ", "subitem_relation_type_select": "DOI"}}]}, "item_8_relation_17": {"attribute_name": "関連サイト", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "https://link.springer.com/article/10.1007/s10965-018-1585-4"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://link.springer.com/article/10.1007/s10965-018-1585-4", "subitem_relation_type_select": "URI"}}]}, "item_8_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1022-9760", "subitem_source_identifier_type": "ISSN"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "metadata only access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_14cb"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "フェルナンデス, マドリッド ジョーダン"}], "nameIdentifiers": [{"nameIdentifier": "495735", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "ジョー"}], "nameIdentifiers": [{"nameIdentifier": "495736", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "植木, 悠二"}], "nameIdentifiers": [{"nameIdentifier": "495737", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Lucille, V. Abad(Philippine Nuclear Research Institute)"}], "nameIdentifiers": [{"nameIdentifier": "495738", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "山延, 健 (群馬大学)"}], "nameIdentifiers": [{"nameIdentifier": "495739", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "瀬古, 典明"}], "nameIdentifiers": [{"nameIdentifier": "495740", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "フェルナンデス マドリッド ジョーダン", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "495741", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "植木 悠二", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "495742", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "瀬古 典明", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "495743", "nameIdentifierScheme": "WEKO"}]}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion"}]}, "item_type_id": "8", "owner": "1", "path": ["1"], "permalink_uri": "https://repo.qst.go.jp/records/49137", "pubdate": {"attribute_name": "公開日", "attribute_value": "2018-08-13"}, "publish_date": "2018-08-13", "publish_status": "0", "recid": "49137", "relation": {}, "relation_version_is_last": true, "title": ["Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion"], "weko_shared_id": -1}
Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion
https://repo.qst.go.jp/records/49137
https://repo.qst.go.jp/records/4913765179cda-2e16-4515-bcfc-b491050af410
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2018-08-13 | |||||
タイトル | ||||||
タイトル | Enhanced amination and adsorption performance of functional copolymer synthesized via RAFT-mediated radiation grafting in emulsion | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
フェルナンデス, マドリッド ジョーダン
× フェルナンデス, マドリッド ジョーダン× ジョー× 植木, 悠二× Lucille, V. Abad(Philippine Nuclear Research Institute)× 山延, 健 (群馬大学)× 瀬古, 典明× フェルナンデス マドリッド ジョーダン× 植木 悠二× 瀬古 典明 |
|||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Grafted polymer substrates bearing diglycol amic acid (DA) ligands for Eu and Sm adsorption were prepared using a two-step post-grafting modification of polyethylene/polypropylene-g-poly(glycidyl methacrylate) (PE/PP-g-PGMA) that was synthesized through reversible addition-fragmentation chain transfer (RAFT)-mediated γ-radiation induced graft polymerization in emulsion phase. The PE/PP-g-PGMA prepared with RAFT mediation exhibited better reactivity towards amination reaction at 40 °C than the graft copolymers prepared without RAFT mediation, with the epoxide to amino group conversion of the former exceeding the latter by as much as 20%. The DA ligands were incorporated to the aminated graft copolymer by subsequent reaction with diglycolic anhydride to yield theDA-modified PE/PP-g-PGMAadsorbent. The effects of pH and competing ions on the uptake of Eu and Sm have been investigated. The DA-modified PE/PP-g-PGMA prepared with RAFT mediation showed higher Eu and Sm adsorption percentage than the DA adsorbent that was synthesized without RAFT mediation. The DA-modified PE/PP-g-PGMA exhibited higher affinity for Eu over Cu and Fe in acidic solutions. |
|||||
書誌情報 |
Journal of Polymer Research 巻 25, p. 193-1-193-11, 発行日 2018-08 |
|||||
出版者 | ||||||
出版者 | Springer | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1022-9760 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1007/s10965-018-1585-4 | |||||
関連サイト | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://link.springer.com/article/10.1007/s10965-018-1585-4 | |||||
関連名称 | https://link.springer.com/article/10.1007/s10965-018-1585-4 |