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Nitroxyl Radicals: Electrochemical Redox Behaviour and Structure-Activity Relationships
https://repo.qst.go.jp/records/48493
https://repo.qst.go.jp/records/48493752cf7be-b09b-4c8a-bef6-bbb1b5f44e39
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2018-02-14 | |||||
タイトル | ||||||
タイトル | Nitroxyl Radicals: Electrochemical Redox Behaviour and Structure-Activity Relationships | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Manda, Sushma
× Manda, Sushma× Nakanishi, Ikuo× Ohkubo, Kei× Yakumaru, Haruko× Matsumoto, Ken-ichiro× Ozawa, Toshihiko× Ikota, Nobuo× Fukuzumi, Shunichi× Anzai, Kazunori× Manda Sushma× 中西 郁夫× 薬丸 晴子× 松本 謙一郎× 小澤 俊彦× 安西 和紀 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Comparative study of electrochemical redox behaviour of five different nitroxyl radicals leads to the direct correlation between one-electron redox potentials and group electronegativity of the beta-substituent on the ring. beta-Substituents with an electron-donating effect caused a negative shift in the one-electron oxidation and one-electron reduction potentials of the nitroxyl radicals. In a similar aspect, beta-substituents with an electron-withdrawing effect behaved oppositely. | |||||
書誌情報 |
Organic & Biomolecular Chemistry 巻 5, 号 24, p. 3951-3955, 発行日 2007-10 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1477-0520 |